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Beilstein J. Org. Chem. 2015, 11, 1960–1972, doi:10.3762/bjoc.11.212
Graphical Abstract
Figure 1: Hydrophilic and/or pH-responsive Ru–alkylidene complexes 1–7 for olefin metathesis.
Scheme 1: Synthesis of 2nd Grubbs-type generation complex 9.
Scheme 2: Synthesis of hexacoordinate, pH-responsive complexes 11 and 12.
Figure 2: ORTEP diagram for H2ITap(DMAP)2Cl2Ru=CH-SPh (12). The positions of the hydrogen atoms were calculat...
Scheme 3: ROMP reactions conducted under microemulsion conditions.
Scheme 4: Proposed formation of catalytic species 14 and 15 under emulsion ROMP conditions.
Figure 3: AFM image produced from COE/DCPD latex film. Measurement: AFM tapping at room temperature, material...